When you breathe you only convert a small proportion of the oxygen in the 
air to carbon dioxide. This carbon dioxide will react with the alkali in the 
developer reducing the pH very slightly.
I would suggest using an 'air' canister like the one used for cleaning the 
negs. These contain one of the freon group compounds (usually HFC134a) which 
will displace the air and reduce oxidation.
Keith.
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Keith Dowsett         "Variables won't; constants aren't."                   
           
E-mail: kdowsett@rpms.ac.uk   
WWW:    http://kd.rpms.ac.uk/index.html